She’s not in Nashville anymore, Toto! After a string of starring roles in musicals like Chicago and Mamma Mia!, Country superstar Jennifer Nettles is joining the ranks of stars reinventing songs from the hit musical Wicked — appearing in the show’s #OutOfOz: Wicked Studio Sessions video series. PEOPLE has the first look at the 43-year-old Grammy winner’s take on “No Good Deed,” one of two tunes Nettles tackles in the popular YouTube show — which has seen Wicked alums like Idina Menzel, Kristin Chenoweth, Aaron Tveit and more take a new stab at Stephen Schwartz’s songs. For Nettles, the opportunity to tackle Wicked‘s songs was “a dream come true.” “I love the music so much,” she told PEOPLE from the set of the shoot.

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